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Plate reactors running under continuous conditions have emerged as candidates to replace batch reactors, primarily in fine chemicals and pharmaceuticals production. One of the advantages of the plate reactor design is that it allows for efficient temperature control of the reacting ... Mehr lesen
Removing halogen groups from hydrocarbons is an important reaction step in several chemical processes. One application is water purification. Other examples involve organic synthesis, where the removal of halogen groups serves as a starting point for carbon-carbon coupling reactions. ... Mehr lesen
This is a model of the secondary current distribution in a zinc electrowinning cell. The model investigates the impact on the current distribution when changing the electrode alignment in a parametric study. The geometry is in 2D. Mehr lesen
Due to its high capacity, silicon (Si) is often added to graphite in the negative electrode of lithium-ion batteries. Silicon–graphite blended electrodes may exhibit significant thermodynamic voltage hysteresis (“path dependence”) because the equilibrium potential of the lithium–silicon ... Mehr lesen
A fuel cell unit cell is modeled using the full Butler-Volmer expression for the anodic and cathodic charge transfer reactions. The anodic and cathodic overpotentials depend on the local ionic and electronic potentials, which are obtained from the charge balance equations for ionic and ... Mehr lesen
This model simulates atmospheric galvanic corrosion of a busbar, which includes a copper flange, an aluminum alloy flange in contact with a zinc nut and bolt. The Secondary Current Distribution interface is used to solve for the electric potential in electrode domain and Current ... Mehr lesen
The zinc bromine redox flow battery is an electrochemical energy storage technology suitable for stationary applications. Compared to other flow battery chemistries, the Zn-Br cell potentially features lower cost, higher energy densities and better energy efficiencies. In the cell ... Mehr lesen
In a redox flow battery electrochemical energy is stored as redox couples in the electrolyte, which is stored in tanks outside the electrochemical cell. During operation, electrolyte is pumped through the cell and, due to the electrochemical reactions, the individual concentrations of ... Mehr lesen
In a polymer electrolyte membrane fuel cell (PEMFC), water is produced at the cathode. The cell is also fed with water vapor via the inlet gas streams, in order to keep the polymer electrolyte membrane humidified. If the water partial pressure in the gas phase exceeds the vapor ... Mehr lesen
In small PEM fuel cell systems (in the sub-100 W range) no active devices for cooling or air transport are normally used. This is due to the desire to minimize parasitic power losses from pumps and fans, and to reduce the system complexity, size, and cost. The reactants at the cathode ... Mehr lesen