Discussion Closed This discussion was created more than 6 months ago and has been closed. To start a new discussion with a link back to this one, click here.
transparent boundary condition with reaction for PNP model in 1D
Posted 20.08.2019, 04:34 GMT-4 Battery Design, Chemical Reaction Engineering, Electrochemistry Version 5.4 0 Replies
Please login with a confirmed email address before reporting spam
I am implementing a PNP model of a RFB considering 5 species initially in steady-state.
I am working with the math module in COMSOL in a 1D problem considering the cathode and membrane. The anode is only included in the boundary of the membrane where a redox reaction takes place, so there is a source term for one species only.
In this anodic boundary, I hoped not to set the concentrations since I don't know them, but to put a transparent BC so that the flux of species can leave the membrane.
When I tried to include the source term at the anodic boundary with a flux BC, COMSOL asks to set the flux for all species, but I don't want a zero flow for the other species. So I added a variables section for the anode boundary where I defined the source term for one species and implemented a flux BC for the 5 species where I just wrote the Nernst-Planck equation based on the concentration and potential variables.
I am not sure if this is the correct way to implement this condition(?), and I find the problem that for certain conditions of SOC and applied current I get a negative profile on the membrane. I think that the anodic BC is probably not correct and I am not restricting the problem correctly.
Does anyone know the correct way to implement a transparent boundary with reaction?
Hello Catalina Pino
Your Discussion has gone 30 days without a reply. If you still need help with COMSOL and have an on-subscription license, please visit our Support Center for help.
If you do not hold an on-subscription license, you may find an answer in another Discussion or in the Knowledge Base.